Electrode Materials for Flexible Electrochromics.

Abstract

Flexible electrochromic devices (ECDs) represent a distinctive category in optoelectronics, leveraging advanced materials to achieve tunable coloration under applied electric voltage. This review delves into recent advancements in electrode materials for ECDs, with a focus on silver nanowires, metal meshes, conductive polymers, carbon nanotubes, and transparent conductive ceramics. Each material is evaluated based on its manufacturing methods and integration potential. The analysis highlights the prominent role of transparent conductive ceramics and conductive polymers due to their versatility and scalability, while also addressing challenges such as environmental stability and production costs. Use of other alternative materials, such as metal meshes, carbon materials, nanowires and others, are presented here as a comparison as well. Emerging hybrid systems and advanced coating techniques are identified as promising solutions to overcome limitations regarding flexibility and durability. This review underscores the critical importance of electrode innovation in enhancing the performance, sustainability, and application scope of flexible ECDs for next-generation technologies.